In November 2005, Pallett showed the nation she could really sing and won an unaired episode of Celebrity Stars in Their Eyes as Gloria Estefan. In January 2006, she appeared in the ITV entertainment singing show Soapstar Superstar, finishing fourth in January 2006, and raising over £70,000 for her supported charity the Eden Valley Hospice Jigsaw Appeal. It was on this show that she fell in love with her co-star Richard Fleeshman and despite a 6 year age gap, the couple went on to become one of soap's hottest couples before they split in 2008. Pallett landed several front covers in profiled modelling features in international magazines, catching the eye of Kanye West who mentioned her on his website after seeing one of her editorial shoots. She regularly topped the 'sexiest' poll awards, cementing her as one of the 100 Most Sexiest Women in the World by FHM in 2006. Pallett embraced the pin-up status brought on by her soap role and landed photoshoots for Loaded and Maxim.