Born in Delaware, Ohio, Rowland received a majority of his education in public schools and, due to accelerated promotion was able to graduate high school several weeks before his 16th birthday. In the summers during his high school career, Frank was entrusted to run the local weather Service station. This was Rowland's first exposure to systematic experimentation and data collection. After entering Ohio Wesleyan University, Rowland was about to graduate shortly before his 18th birthday. Instead, he was enlisted to the Navy to train radar operators. Rowland was discharged after 14 months as a non commissioned officer. After entering the University of Chicago, Rowland was assigned Willard F. Libby as a mentor and began to study radiochemistry. Rowland's thesis was about the chemical state of cyclotron-produced radioactive bromine atoms. Rowland received his B.A. from Ohio Wesleyan University in 1948. He then earned his M.S. in 1951 and his Ph.D. in 1952, both from the University of Chicago.